Mereological atomism is the thesis that everything is ultimately composed of atomic parts, i.e., parts without proper parts. Typically, this thesis is characterized by an axiom stating that everything has atomic parts. The present paper argues that the success of this standard characterization depends on how the notions of sum and composition are defined. In particular, we put forward a novel definition of mereological sum that: (i) is not equivalent to existing definitions in the literature, if no strong decomposition principle (...) is assumed; (ii) can be used to argue that the standard characterization of atomism fails, because having atomic parts is not sufficient to be a sum of atoms; and (iii) provides a purely mereological distinction between structured and unstructured wholes, contributing to the ongoing debate on this crucial topic. (shrink)